(PhysOrg.com) -- Scientists have known for generations that hot water can sometimes freeze faster than cold, an effect known as the Mpemba effect, but until now have not understood why. Several theories have been proposed, but one scientist believes he has the answer. //

In his experiments, Brownridge took two water samples at the same temperature and placed them in a freezer. He found that one would usually freeze before the other, presumably because of a slightly different mix of impurities. He then removed the samples from the freezer, warmed one to room temperature and the other to 80°C and then froze them again. The results were that if the difference in freezing point was at least 5°C, the one with the highest freezing point always froze before the other if it was heated to 80°C and then re-frozen.

Brownridge said the hot water cools faster because of the bigger difference in temperature between the water and the freezer, and this helps it reach its freezing point before the cold water reaches its natural freezing point, which is at least 5°C lower. He also said all the conditions must be controlled, such as the location of the samples in the freezer, and the type of container, which he said other researchers had not done.

The effect now known as the Mpemba effect was first noted in the 4th century BC by Aristotle, and many scientists have noted the same phenomenon in the centuries since Aristotle’s time. It was dubbed the Mpemba effect in the 1960s when schoolboy Erasto Mpemba from Tanzania claimed in his science class that ice cream would freeze faster if it was heated first before being put in the freezer. The laughter ended only when a school inspector tried the experiment himself and vindicated him.

More information: Mpemba effect - Wiki article;
James D. Brownridge web page;
Mpemba Effect scientific paper, March 2010, by James D. Brownridge;
via Newscientist

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